Absorption and desorption behaviour of the total flavones from Glycyrrhiza residues on macroporous adsorption resins

YUAN Ru-nan; HU Hao-bin; HAN Shun-yu; WANG Zong-bo

doi:10.13386/j.issn1002-0306.2016.23.029

Article Contents

Article Navigation > Science and Technology of Food Industry > 2016 > (23): 199-205

YUAN Ru-nan, HU Hao-bin, HAN Shun-yu, WANG Zong-bo. Absorption and desorption behaviour of the total flavones from Glycyrrhiza residues on macroporous adsorption resins[J]. Science and Technology of Food Industry, 2016, (23): 199-205. doi: 10.13386/j.issn1002-0306.2016.23.029

Citation:

YUAN Ru-nan, HU Hao-bin, HAN Shun-yu, WANG Zong-bo. Absorption and desorption behaviour of the total flavones from Glycyrrhiza residues on macroporous adsorption resins[J]. Science and Technology of Food Industry, 2016, (23): 199-205. doi: 10.13386/j.issn1002-0306.2016.23.029

Citation:

YUAN Ru-nan, HU Hao-bin, HAN Shun-yu, WANG Zong-bo. Absorption and desorption behaviour of the total flavones from Glycyrrhiza residues on macroporous adsorption resins[J]. Science and Technology of Food Industry, 2016, (23): 199-205. doi: 10.13386/j.issn1002-0306.2016.23.029

PDF( 1306 KB)

Absorption and desorption behaviour of the total flavones from Glycyrrhiza residues on macroporous adsorption resins

doi: 10.13386/j.issn1002-0306.2016.23.029

College of Food Science and Engineering,Gansu Agricultural University
College of Chemistry and Chemical Engineering,Longdong University
Qingyang Zhongkai Agricultural Products Limited Liability Company

Received Date: 2016-04-27

Abstract

Abstract

The adsorption and desorption behaviours of macroporous resins for enriching total flavonoids from Glycyrrhiza residues were investigated.Five macroporous resins were studied using the static adsorption method.Additionally two representative resins( AB-8 and SP825) were chosen for adsorption thermodynamics and kinetics model studies,the conditions for purifying were optimized. The kinetics results showed that the whole adsorption process can be described better by the pseudo-second order kinetics model.The thermodynamics results showed that the adsorption process fited the Freundlich isothermal model,the adsorption of the representative resins was an exothermic and physical adsorption process. The optimum process conditions for purifying the total flavonoids from Glycyrrhiza residues using AB-8 resin were determined as follows: sample concentration of 1.089 mg / m L,flow velocity of 3 m L / min,sample volume of 2 BV,and amount of 80% ethanol as desorption solvent 3 BV,flow velocity of 1.5 m L / min. By this time the desorption rate was 91.67%. The purity was increased to 53.43%,which showed that AB-8 macroporou resin had better adsorption property. It can be used to purify and separate total flavonoids from Glycyrrhiza residues.
- macroporous adsorption resins,
- Glycyrrhiza residues,
- total flavonoids,
- adsorption behaviours,
- purification

FullText(HTML)

References(25)

References

[1]	谷会岩.中国甘草资源生态学研究[D].哈尔滨:东北林业大学,2001:5-10.
[2]	崔永明.甘草次生代谢产物分离纯化研究[D].武汉:华中科技大学,2005:1-20.
[3]	Kim Y W,Ki S H,Lee J R,et al.Liquiritigenin,an aglycone of liquiritin in Glycyrrhiza Radix,prevents acute liver injuries in rats induced by acetam inophen with or without buthionine sulfoximine[J].Chemico-biological interactions,2006,161(2):125-138.
[4]	赵虹,蒋江涛,郑秋生.甘草查尔酮A药理作用研究进展[J].中国中药杂志,2013,38(22):3814-3818.
[5]	吴碧华,龙存国.甘草总黄酮清除羟自由基作用的体外实验探讨[J].川北医学院学报,2001,16(3):3-5.
[6]	Tamir S,Eizenberg M,Somjen D,et al.Estrogen-like activity of glabrene and other constituents isolated from licorice root[J].Journal Steroid Biochemistry and Molecular Biology,2001,78(3):291-298.
[7]	方诗琦,冷康,段金廣,等.甘草药渣中黄酮类成分及其抗氧化活性的研究[J].中成药,2015,37(11):2443-2448.
[8]	Zhou B,Zhang J Z,Wu S S,et al.The influence of compatibility of processed radix aconite kusnezoffii on the pharmacokinetic of four components in Glycyrrhiza uralensis Fisch[J].Journal of Ethnopharmacology,2015,169(2):1-7.
[9]	Trupti W C,Virednra K R.Separation of glycyrrhizic acid from licorice root extract using macroporous resin[J].Food and Bioproducts Processing,2015,93(12):51-57.
[10]	马彩梅.甘草及甘草渣的综合利用研究进展[J].现代农业科技,2015,13(1):121-122.
[11]	李俶,倪永年,李莉.大孔吸附树脂分离纯化槲寄生中黄酮的研究[J].食品科学,2008,29(2):68-71.
[12]	Dong Y,Zhao M M,Sun D G.Absorption and desorption behaviour of the flavonoids from Glycyrrhiza glabra L.leaf on macroporous adsorption resins[J].Food Chemistry,2015,168(2):538-545.
[13]	王国军,唐辉,张淑兰,等.大孔树脂纯化核桃隔膜总黄酮的工艺研究[J].中草药,2013,44(19):2688-2692.
[14]	洪雪娥,高荫榆,罗丽萍,等.大孔树脂对薯蔓黄酮吸附分离特性研究[J].食品科学,2006,27(10):423-427.
[15]	Lin L Z,Zhao H F,Ding Y,et al.Macroporous resin purification behavior of phenolics and rosmarinic acid from Rabdosia serra(Maxim)Hara leaf[J].Food Chemistry,2012,130(1):417-424.
[16]	Gulay B,Beguma,Yakupa M.Adsorption kinetics and thermodynamic parameters of cationic dyes from aqueous solutions by using a new strong cation-exchange resin[J].Chemical Engineering Journal,2009,152(2-3):339-346.
[17]	廉宜君,孙萍,陈韩英,等.大孔树脂吸附解吸甘草黄酮效果研究[J].中国中医药信息杂志,2013,20(9):49-52.
[18]	Guo B,Hong L,Jiang H X.Macroporous,poly(calcium acrylate-divinylbenzene)bead-A selective orthophosphate sorbent[J].Industrial and Engineering Chemistry Research,2003,42(22):5559-5567.
[19]	Ayrancie,Hoda N.Adsorption kinetics and isotherms of pesticides onto activated carbon-cloth[J].Chemosphere,2005,60(11):1600-1607.
[20]	Silva E M,Rogez H,Silva Iq,et al.Improving the desorption of Inga edulis flavonoids from macroporous resin:Towards a new model to concentrate bioactive compounds[J].Food and Bioproducts Processing,2012,167(4):358-364.
[21]	Francisco A,Tomas B,Blazquzema,et al.A comparative study of different amberlite XAD resins in flavonoid analysis[J].Phytochemical Analysis,1992,3(4):178-181.
[22]	Liu Y F,Liu J X,Chen X F,et al.Preparative separation and purification of lycopene from tomato skins extracts by macroporous adsorption resins[J].Food Chemistry,2010,123(4):1027-1034.
[23]	Gokmen V,Serpen A.Equilibrium and kinetic studies on the adsorption of dark colored compounds from apple juice using adsorbent resins[J].Journal of Food Engineering,2002,53(3):221-227.
[24]	董媛媛,邓翀,柴思佳.大孔树脂吸附南五味子总三萜的动力学和热力学分析[J].中国实验方剂学杂志,2014,20(17):5-9.
[25]	焦岩,王振宇.大孔树脂纯化大果沙棘果渣总黄酮的工艺研究[J].食品科学,2010,31(16):16-20.