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中国精品科技期刊2020
王华瑜,程林,姜涛,等. AgCl-姜黄素-g-C3N4复合杀菌剂的结构表征及杀菌性能J. 食品工业科技,2025,46(21):249−255. doi: 10.13386/j.issn1002-0306.2014120059.
引用本文: 王华瑜,程林,姜涛,等. AgCl-姜黄素-g-C3N4复合杀菌剂的结构表征及杀菌性能J. 食品工业科技,2025,46(21):249−255. doi: 10.13386/j.issn1002-0306.2014120059.
WANG Huayu, CHENG Lin, JIANG Tao, et al. Structure Characterization and Antibacterial Performance of AgCl-Curcumin-g-C3N4J. Science and Technology of Food Industry, 2025, 46(21): 249−255. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2014120059.
Citation: WANG Huayu, CHENG Lin, JIANG Tao, et al. Structure Characterization and Antibacterial Performance of AgCl-Curcumin-g-C3N4J. Science and Technology of Food Industry, 2025, 46(21): 249−255. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2014120059.

AgCl-姜黄素-g-C3N4复合杀菌剂的结构表征及杀菌性能

Structure Characterization and Antibacterial Performance of AgCl-Curcumin-g-C3N4

  • 摘要: 针对表面活性位点少的g-氮化碳在杀灭致病性微生物时性能低的问题,本文以姜黄素、硝酸银和尿素为原料,通过热解法制备了AgCl-姜黄素-g-C3N4复合杀菌剂。对比了不同姜黄素负载量的AgCl-Cur-g-C3N4杀菌活性效果,研究了姜黄素的封装率,分析了AgCl-Cur-g-C3N4物理性能和结构变化,采用平板菌落计数法和抑菌圈法考察了该复合杀菌剂对大肠杆菌和金黄色葡萄球菌的杀菌性能,并考察了其细胞毒性。结果表明:当姜黄素负载量为0.005 g时,复合杀菌剂AgCl-Cur-g-C3N4的杀菌效果最佳,此时姜黄素的封装率达到了85.7%±0.3%。复合杀菌剂中姜黄素与AgCl均匀分散在g-C3N4的片层结构中,银以银离子状态存在。与AgCl-g-C3N4杀菌剂相比,在姜黄素和AgCl的共同作用下,复合杀菌剂在自然光下照射1 h后对大肠杆菌和金黄色葡萄球菌去除率达到100%。由此表明AgCl-Cur-g-C3N4复合杀菌剂的杀菌效果好,且具有较低的细胞毒性。该复合杀菌剂既有较好杀菌性能,又是绿色环保功能材料,作为一种具有广谱杀菌效果的新型杀菌材料,有望在食品卫生领域应用。

     

    Abstract: In order to solve the low performance of killing pathogenic microorganisms for carbon nitride with few surface active sites, AgCl-curcumin-g-C3N4 compound fungicides were prepared by pyrolysis using curcumin, silver nitrate and urea as raw materials. The antibacterial activity of AgCl-Cur-g-C3N4 with different curcumin loads was compared and the encapsulation efficiency of curcumin was investigated in this study. The physical properties and structural changes of the AgCl-Cur-g-C3N4 were analyzed and its cytotoxicity was also investigated. The catalytic bactericidal performance against Escherichia coli and Staphylococcus aureus was investigated by plate colony counting method and bacteriostatic zone method. The results showed that when the loading amount of curcumin was 0.005 g, the composite fungicide AgCl-Cur-g-C3N4 had the best antibacterial effect, and the encapsulation rate of curcumin reached 85.7%±0.3%. Curcumin and AgCl were uniformly dispersed in the layer structure of g-C3N4, and silver existed in the state of silver ion. Compared with AgCl-g-C3N4, under the synergistic action of curcumin and AgCl, the removal rate of Escherichia coli and Staphylococcus aureus reached 100% after exposure to natural light for 1.0 h. The compound fungicides had the excellent bactericidal performance and the lower cytotoxicity. The compound bactericide not only had good bactericidal performance, but also was a green functional material. As a new bactericidal material with broad spectrum bactericidal effect, it was expected to be used in the field of food hygiene.

     

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