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中国精品科技期刊2020
褚倩倩,靳博宇,张浩鹏,等. 不同种类葡聚糖对明胶精油可食膜的性能及结构的影响[J]. 食品工业科技,2025,46(10):260−270. doi: 10.13386/j.issn1002-0306.2024060027.
引用本文: 褚倩倩,靳博宇,张浩鹏,等. 不同种类葡聚糖对明胶精油可食膜的性能及结构的影响[J]. 食品工业科技,2025,46(10):260−270. doi: 10.13386/j.issn1002-0306.2024060027.
CHU Qianqian, JIN Boyu, ZHANG Haopeng, et al. Effects of Different Types of Pectin on the Properties and Structure of Gelatin Essential Oil Edible Films[J]. Science and Technology of Food Industry, 2025, 46(10): 260−270. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2024060027.
Citation: CHU Qianqian, JIN Boyu, ZHANG Haopeng, et al. Effects of Different Types of Pectin on the Properties and Structure of Gelatin Essential Oil Edible Films[J]. Science and Technology of Food Industry, 2025, 46(10): 260−270. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2024060027.

不同种类葡聚糖对明胶精油可食膜的性能及结构的影响

Effects of Different Types of Pectin on the Properties and Structure of Gelatin Essential Oil Edible Films

  • 摘要: 为葡聚糖在可食膜中的应用提供数据支持,以期开发出性能更好的可食性薄膜。本研究将肉桂醛、丁香酚和茴香醛精油进行复配,探究其对大肠杆菌、绿脓杆菌、枯草芽孢杆菌和兰黑紫色杆菌的抑菌性能。以明胶为主要成膜基质,复合精油为抑菌剂,探究添加不同种类葡聚糖对明胶基可食膜的影响。采用红外光谱、X-射线衍射和扫描电子显微镜对4种复合可食膜进行了结构表征研究。结果表明:精油的最佳组合为体积比1:1的肉桂醛和丁香酚精油。对大肠杆菌和绿脓杆菌最低抑菌浓度为0.156 μL/mL;对枯草芽孢杆菌和兰黑紫色杆菌最低抑菌浓度为0.313 μL/mL。加入葡聚糖可以明显改善明胶基可食膜和明胶基精油可食膜的机械性能、阻隔性能和热稳定性。力学性能断裂时的抗拉力(TS)由35%~40%增长到45%~55%、伸长长度(E)由15~17 MPa提高到20~23 MPa;水蒸气透过率(WVP)可由30.04×10−2 g·mm/(m2·h·kPa)下降至22.31×10−2 g·mm/(m2·h·kPa);油透率(PO)可由139.12 g·mm·m−2·d−1降至108.21 g·mm·m−2·d−1;氧透过率(PV)可由5.72 g/100 g降至3.46 g/100 g。通过红外光谱、X-射线衍射和热稳定分析,可以证明葡聚糖与精油、明胶两种高分子之间有较强的相互作用和较好的相容性。以最低抑菌浓度添加复合精油的膜液对供试菌有明显抑菌效果,抑菌圈从0~5 mm变为15~20 mm,达到中敏。

     

    Abstract: In this study, the essential oils cinnamaldehyde, eugenol, and anisaldehyde were complexed to investigate their bacteriostatic properties against Escherichia coli, Pseudomonas aeruginosa, Bacillus subtilis, and Pseudomonas oryzae. Utilizing gelatin as the primary film-forming matrix and the blended essential oils as bacteriostatic agents, the effects of incorporating various types of dextran into gelatin-based edible films were examined. The objective was to provide data to support the use of dextran in edible films, aiming to develop films with enhanced performance. Performance characterization studies of four composite edible films were conducted using infrared spectroscopy, X-ray diffraction, and scanning electron microscopy. The results indicated that the optimal combination of essential oils was a 1:1 ratio of cinnamaldehyde to eugenol, yielding the lowest inhibitory concentration of 0.156 μL/mL for both Escherichia coli and Pseudomonas aeruginosa, and 0.313 μL/mL for Bacillus subtilis and Pseudomonas oryzae. Additionally, the incorporation of dextran significantly enhanced the mechanical properties, barrier properties, and thermal stability of both gelatin-based edible films and those infused with essential oils. Specifically, the mechanical properties improved as follows: tensile strength at break (TS) increased from 35%~40% to 45%~55%, elongation (E) rose from 15~17 MPa to 20~23 MPa, water vapor permeability (WVP) decreased from 30.04×10−2 g·mm/(m²·h·kPa) to 22.31×10−2 g·mm/(m²·h·kPa). Oil permeability (PO) was reduced from 139.12 g·mm·m−2·d−1 to 108.21 g·mm·m−2·d−1, and oxygen permeability (PV) decreased from 5.72 g/100 g to 3.46 g/100 g. Infrared spectroscopy, X-ray diffraction, and thermal stability analyses revealed strong interactions and improved compatibility between the dextran, essential oils, and gelatin. Furthermore, the film solution containing compound essential oil at the lowest inhibitory concentration demonstrated a significant antibacterial effect against the test bacteria, and the inhibition circle changed from 0~5 mm to 15~20 mm, reaching a medium sensitivity.

     

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