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中国精品科技期刊2020
徐涵,陈文田,丁志昆,等. 淀粉基天然甜菜红色素微胶囊的制备、稳定及其应用[J]. 食品工业科技,2025,46(20):212−221. doi: 10.13386/j.issn1002-0306.2024100237.
引用本文: 徐涵,陈文田,丁志昆,等. 淀粉基天然甜菜红色素微胶囊的制备、稳定及其应用[J]. 食品工业科技,2025,46(20):212−221. doi: 10.13386/j.issn1002-0306.2024100237.
XU Han, CHEN Wentian, DING Zhikun, et al. Preparation, Stabilization and Application of Starch-based Natural Betanin Microcapsules[J]. Science and Technology of Food Industry, 2025, 46(20): 212−221. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2024100237.
Citation: XU Han, CHEN Wentian, DING Zhikun, et al. Preparation, Stabilization and Application of Starch-based Natural Betanin Microcapsules[J]. Science and Technology of Food Industry, 2025, 46(20): 212−221. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2024100237.

淀粉基天然甜菜红色素微胶囊的制备、稳定及其应用

Preparation, Stabilization and Application of Starch-based Natural Betanin Microcapsules

  • 摘要: 为提高甜菜红色素的热稳定性,本文以甜菜红色素为研究对象,采用淀粉吸附法和多糖包埋技术相结合制备负载甜菜红色素的淀粉基微胶囊。首先,利用单因素实验筛选淀粉种类、多糖种类、海藻酸钠添加量、抗坏血酸添加量与色素添加量;进一步利用扫描电镜(Scanning electron microscope‌,SEM)和傅里叶红外光谱(Fourier transform infrared spectroscopy,FTIR)对微胶囊进行表征并分析其稳定机制;最后,将热稳态化的微胶囊应用于热加工食品中(涂抹甜菜红色素的面饼,沸水蒸制12 min)以验证其效果。结果表明:负载甜菜红色素的淀粉基微胶囊的最佳制备工艺和配方是玉米淀粉,淀粉吸附色素时间2 h,玉米淀粉和色素的质量比30:3,玉米淀粉湿基和海藻酸钠质量比3:0.03,玉米淀粉和抗坏血酸质量比60:1,此条件下微胶囊在蒸汽加热12 min后色素的保留率为73.42%。另外,色素微胶囊的外观呈现深红色且在其FTIR(765 cm−1)中观察到了色素的光谱信息,证明了甜菜红色素被吸附到了淀粉内部;SEM观察到色素微胶囊表面附有薄膜涂层,证明了海藻酸钠包裹在淀粉颗粒外围形成了物理保护层。通过在热加工食品中的应用,加热后色差值ΔE为12.11±0.83(微胶囊)<22.01±2.82(对照),发现该微胶囊具有较高的热稳定性。因此,通过用淀粉吸附色素、抗坏血酸辅色和海藻酸钠包埋相结合可显著提高甜菜红色素的热稳定性,该研究结果可为甜菜红色素在食品加工中的应用提供一定的理论依据和参考。

     

    Abstract: In this paper, the betanin was studied to improve the thermal stability of betanin. Starch-based microcapsules loaded with betanin were prepared by starch adsorption and polysaccharide encapsulation. Firstly, single factor experiment was used to screen starch categories, polysaccharide categories, addition of sodium alginate, addition of ascorbic acid and addition of betanin. Then, the microcapsules were characterized by scanning electron microscopy (SEM) and Fourier transform infrared spectrometer (FTIR), and the stability mechanism was also further analyzed. Finally, the thermostable betanin microcapsules were applied to the hot-processed food to verify their application effect (the betanin-colored dough was steamed in boiling water for 12 min). Results showed that the optimum preparation technology and formula of starch-based microcapsules loaded with betanin were corn starch, the best adsorption time of betanin by starch was 2 h, the best mass ratio of corn starch to betanin was 30:3, the best ratio of corn starch (wet base) to sodium alginate was 3:0.03, the best ratio of corn starch to ascorbate was 60:1, and the best retention rate of betanin was 73.42% after steam heating for 12 min. In addition, the appearance of the betanin microcapsules was dark red with fine particles. SEM indicated that the betanin was adsorbed into the starch interior, and sodium alginate wrapped around the starch particles to form a physical protective layer. FTIR (765 cm−1) also confirmed that the betanin had been successfully loaded into the microcapsules. Through application in thermally processed foods, the color difference value ΔE after heating was 12.11+0.83 (microcapsules)<22.01+2.82 (control group), indicating the highthermal stability of microcapsules. Therefore, the heat stability of betanin can be improved by using starch as adsorbing material, ascorbic acid as color fixative and sodium alginate as embedding agent, the results also provide some theoretical basis and reference for the application of betanin in food processing.

     

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