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中国精品科技期刊2020
晁玥,卢秋予,湛胜楠,等. 金属盐离子调控糖基化鱼明胶乳液凝胶性能及结构特性研究J. 食品工业科技,2026,47(13):1−9. doi: 10.13386/j.issn1002-0306.2025030038.
引用本文: 晁玥,卢秋予,湛胜楠,等. 金属盐离子调控糖基化鱼明胶乳液凝胶性能及结构特性研究J. 食品工业科技,2026,47(13):1−9. doi: 10.13386/j.issn1002-0306.2025030038.
CHAO Yue, LU Qiuyu, ZHAN Shengnan, et al. Research on the Performance and Structural Characteristics of Metal Salt Ion-regulated Sugar-based Fish Gelatin Emulsion GelJ. Science and Technology of Food Industry, 2026, 47(13): 1−9. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2025030038.
Citation: CHAO Yue, LU Qiuyu, ZHAN Shengnan, et al. Research on the Performance and Structural Characteristics of Metal Salt Ion-regulated Sugar-based Fish Gelatin Emulsion GelJ. Science and Technology of Food Industry, 2026, 47(13): 1−9. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2025030038.

金属盐离子调控糖基化鱼明胶乳液凝胶性能及结构特性研究

Research on the Performance and Structural Characteristics of Metal Salt Ion-regulated Sugar-based Fish Gelatin Emulsion Gel

  • 摘要: 为开发高品质低盐鱼明胶乳液凝胶制品,本研究系统探究了不同浓度梯度(100、200、400、800 mmol/L)氯化钾(KCl)与氯化钙(CaCl2)对糖基化鱼明胶乳液凝胶的凝胶性能及结构特性的影响。通过粒径、Zeta电位、质构剖面分析(TPA)、持水力、流变特性及扫描电镜(SEM)等实验分析表明,随着盐离子浓度升高,糖基化鱼明胶乳液凝胶的Zeta电位绝对值、凝胶强度、硬度、胶粘性、咀嚼性和持水力均显著降低,粒径增大,且氯化钙对凝胶特性的影响显著高于氯化钾。在高浓度盐离子(800 m mol/L)条件下,乳液凝胶的粘弹性和抗变形能力显著降低,凝胶网络结构疏松,形成受到显著抑制。研究表明,过量盐离子通过竞争性结合蛋白质极性基团削弱氢键,并通过增强离子强度干扰疏水相互作用,抑制蛋白质分子交联,最终导致凝胶网络结构坍塌,从而降低乳液凝胶的性能。

     

    Abstract: In the pursuit of developing high-quality low-salt fish gelatin emulsion gel products, this study undertook a comprehensive investigation into the effects of varying concentration gradients of potassium chloride (KCl) and calcium chloride (CaCl2) on the gel properties and structural characteristics of glycosylated fish gelatin emulsion gels. Specifically, the concentration gradients examined were 100, 200, 400, and 800 mmol/L. A multifaceted experimental approach was employed, encompassing analyses of particle size, zeta potential, texture profile analysis (TPA), water holding capacity, rheological properties, and scanning electron microscopy (SEM). The results demonstrated that as the salt ion concentration increased, several key parameters exhibited significant changes. The absolute value of Zeta potential, along with gel strength, hardness, adhesiveness, chewiness, and water holding capacity of the glycosylated fish gelatin emulsion gels, were all markedly reduced. In contrast, the particle size displayed an increasing trend. Furthermore, the impact of CaCl2 on the gel properties was substantially more pronounced than that of KCl. Under conditions of high salt ion concentration (800 mmol/L), the viscoelasticity and deformation resistance of the emulsion gels were significantly compromised. The gel network structure became loosened, and the formation process was considerably hindered. The findings revealed that excess salt ions disrupted hydrogen bonding and hydrophobic interactions, thereby inhibiting protein cross - linking and ultimately leading to a reduction in the properties of the emulsion gels.

     

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