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中国精品科技期刊2020
覃海丽,赵巧丽,张杰良,等. 亚麻籽胶对甲基纤维素泡沫模板气凝胶孔隙结构和机械性能的调控作用J. 食品工业科技,2026,47(16):1−11. doi: 10.13386/j.issn1002-0306.2025080149.
引用本文: 覃海丽,赵巧丽,张杰良,等. 亚麻籽胶对甲基纤维素泡沫模板气凝胶孔隙结构和机械性能的调控作用J. 食品工业科技,2026,47(16):1−11. doi: 10.13386/j.issn1002-0306.2025080149.
QIN Haili, ZHAO Qiaoli, Kit-Leong Cheong, et al. Modulation of Pore Structure and Mechanical Properties of Methylcellulose Foam Template Aerogel by Linseed GumJ. Science and Technology of Food Industry, 2026, 47(16): 1−11. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2025080149.
Citation: QIN Haili, ZHAO Qiaoli, Kit-Leong Cheong, et al. Modulation of Pore Structure and Mechanical Properties of Methylcellulose Foam Template Aerogel by Linseed GumJ. Science and Technology of Food Industry, 2026, 47(16): 1−11. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2025080149.

亚麻籽胶对甲基纤维素泡沫模板气凝胶孔隙结构和机械性能的调控作用

Modulation of Pore Structure and Mechanical Properties of Methylcellulose Foam Template Aerogel by Linseed Gum

  • 摘要: 本研究将不同浓度亚麻籽胶(Linseed gum,LG)和甲基纤维素(Methylcellulose,MC)混合,系统分析了LG浓度对复合多糖水泡沫性质的影响,并通过傅里叶变换红外光谱、扫描电镜、热重分析等技术对复合多糖气凝胶(MC-LG)的微观形貌、孔隙结构、热稳定性和机械性能进行表征。结果表明,复合多糖溶液粘度随LG浓度(0.1wt%~0.5wt%)增加显著提高,而泡沫膨胀率呈先降低后升高趋势,并在0.4wt%时达到最大值(7.59%)。与纯MC水泡沫(76.40 μm)相比,MC-0.4wt% LG水泡沫气泡分布更加均匀,平均尺寸减小至59.11 μm,且储存48 h后仍保持较好的稳定性。扫描电镜和红外光谱分析表明,MC与LG分子间形成了氢键相互作用,且含0.4wt% LG的MC-LG气凝胶呈现较为均匀的蜂窝状多孔结构。机械性能结果显示,MC-0.4wt% LG气凝胶杨氏模量达到0.0982 MPa,显著高于单一MC气凝胶(0.0288 MPa),屈服强度和抗压强度也得到显著提升。综上所述,LG浓度为0.4wt%时,MC-LG气凝胶具有均匀致密的孔隙结构、良好的热稳定性和优异的机械性能,整体性能较为理想。本研究可为高性能多糖基气凝胶在食品和生物医药等领域的应用提供技术参考。

     

    Abstract: In this study, different concentrations of Linseed gum (LG) and Methylcellulose (MC) were mixed, and the effects of LG concentration on the properties of composite polysaccharide water foam were systematically analyzed. The microstructure, pore structure, thermal stability and mechanical properties of composite polysaccharide aerogel (MC-LG) were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy and thermogravimetric analysis. The results showed that the viscosity of complex polysaccharide solution increased significantly with the increase of LG concentration (0.1wt%~0.5wt%), while the foam expansion rate first decreased and then increased, and reached the maximum value (7.59%) at 0.4wt%. Compared with pure MC water foam (76.40 μm), the bubble distribution of MC-0.4wt% LG water foam was more uniform, and the average size was reduced to 59.11 μm, and it still maintains good stability after 48 h storage. Scanning electron microscope and infrared spectrum analysis showed that hydrogen bond interaction was formed between MC and LG molecules, and MC-LG aerogel containing 0.4wt% LG presents a relatively uniform honeycomb porous structure. The results of mechanical properties showed that the Young's modulus of MC-0.4wt% LG aerogel reaches 0.0982 MPa, which was significantly higher than that of single MC aerogel (0.0288 MPa), and the yield strength and compressive strength are also significantly improved. To sum up, when the concentration of LG is 0.4wt%, MC-LG aerogel has uniform and compact pore structure, good thermal stability and excellent mechanical properties, and the overall performance is ideal. This study can provide technical reference for the application of high-performance polysaccharide-based aerogels in food and biomedicine.

     

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