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中国精品科技期刊2020
李娅,帅希祥,张明,等. 不同酯化度的芒果皮果胶对芒果浊汁稳定性的影响及动力学研究J. 食品工业科技,2026,47(13):1−13. doi: 10.13386/j.issn1002-0306.2025060189.
引用本文: 李娅,帅希祥,张明,等. 不同酯化度的芒果皮果胶对芒果浊汁稳定性的影响及动力学研究J. 食品工业科技,2026,47(13):1−13. doi: 10.13386/j.issn1002-0306.2025060189.
LI Ya, SHUAI Xixiang, ZHANG Ming, et al. Influence and Kinetic Study of Mango Peel Pectin with Different Esterification Degrees on the Stability of Mango JuiceJ. Science and Technology of Food Industry, 2026, 47(13): 1−13. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2025060189.
Citation: LI Ya, SHUAI Xixiang, ZHANG Ming, et al. Influence and Kinetic Study of Mango Peel Pectin with Different Esterification Degrees on the Stability of Mango JuiceJ. Science and Technology of Food Industry, 2026, 47(13): 1−13. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2025060189.

不同酯化度的芒果皮果胶对芒果浊汁稳定性的影响及动力学研究

Influence and Kinetic Study of Mango Peel Pectin with Different Esterification Degrees on the Stability of Mango Juice

  • 摘要: 以台农1号芒果为原料,通过超声辅助酸解法提取芒果皮果胶,经碱法脱酯制备得到四种酯化度的果胶(DEMP1~DEMP4,酯化度分别为66.26%、55.32%、47.19%、33.67%)。将果胶添加到芒果浊汁中,评价果胶对浊汁稳定性的影响,并根据Stokes理论预测重力沉降时间,通过25~45 ℃加速贮藏实验预测芒果浊汁的货架期。结果表明,添加低酯芒果皮果胶(DEMP3/DEMP4)能有效地提高芒果浊汁的稳定性。其中添加DEMP4的芒果浊汁离心沉淀率达44.46%,悬浮稳定性提升26.8%,不稳定性指数降低25.47%,重力沉降时间从对照组的0.79个月延长至6.30个月;采用Boltzmann与Logistic模型拟合沉降动力学,发现DEMP4能够显著延长沉降反弯点时间;DEMP4的zeta电位达−36.09 mV,持水性达14.72 g/g,在加速贮藏中粒径增幅最低,这些理化特性与浊汁稳定性提升呈显著正相关。建立了离心沉淀率的吉布斯自由能与温度之间、感官值与离心沉淀率之间的回归方程,获得了浊汁稳定动力学及热力学模型,根据模型推测了芒果浊汁在不同温度下的稳定性时间。25 ℃下,与未添加果胶的芒果浊汁相比,添加了DEMP1、DEMP2、DEMP3、DEMP4的芒果浊汁的稳定时间从21 d分别延长至30、60、185、195 d。除芒果汁外,预测模型残差变异系数均小于15%,表明该模型具有高预测精度。

     

    Abstract: Pectin was extracted from the peels of Tainong No.1 mango via ultrasound-assisted acid hydrolysis, and four types of pectins with different degrees of esterification (DE) were prepared by alkaline deesterification, namely DEMP1, DEMP2, DEMP3, and DEMP4, with DE values of 66.26%, 55.32%, 47.19%, and 33.67%, respectively. These pectins were added to mango cloudy juice to evaluate their effects on the stability of the juice. Based on Stokes' theory, the gravitational sedimentation time was predicted, and the shelf life of mango cloudy juice was estimated through accelerated storage experiments conducted at 25~45 ℃. The results showed that the addition of low-ester mango peel pectins (DEMP3/DEMP4) effectively improved the stability of mango cloudy juice. Specifically, the juice added with DEMP4 exhibited a centrifugal precipitation rate of 44.46%, with the suspension stability increased by 26.8% and the instability index reduced by 25.47%. Moreover, the gravitational sedimentation time was extended from 0.79 months (control group) to 6.30 months. The sedimentation kinetics were fitted using the Boltzmann and Logistic models, and it was found that DEMP4 significantly prolonged the time of the sedimentation inflection point. The zeta potential and water-holding capacity of DEMP4 reached -36.09 mV and 14.72 g/g, respectively, and the particle size increase was the lowest during accelerated storage. These physicochemical properties were significantly positively correlated with the improved stability of the cloudy juice. Regression equations were established between the Gibbs free energy of centrifugal precipitation rate and temperature, as well as between sensory scores and centrifugal precipitation rate, yielding kinetic and thermodynamic models for juice stability. Based on the models, the stability time of the mango cloudy juice at different temperatures was predicted. At 25 ℃, compared with the control group (without pectin addition) which had a stability duration of 21 days, the stability durations of the juices added with DEMP1, DEMP2, DEMP3, and DEMP4 were extended to 30, 60, 185 and 195 days, respectively. Except for mango juice, the residual coefficients of variation for the prediction models were all below 15%, confirming their high predictive accuracy.

     

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